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Kinetics of solvent exchange of hexakis(N,N-dimethylformamide)chromium(III) ion in N,N-dimethylformamide. Temperature and pressure effects and mechanism

✍ Scribed by Lo, S. T. D.; Swaddle, T. W.


Book ID
121430297
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
613 KB
Volume
14
Category
Article
ISSN
0020-1669

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## Abstract The rate of DMF exchange on [Tm (DMF)~8~]^3+^ has been determined by ^1^H‐ and ^13^C‐NMR. linebroadening techniques. ^1^H‐NMR. yields the following solvent exchange parameters; Ξ”__H__\* = 33.2 (Β±0.5) kJ mol^βˆ’1^, Ξ”__S__\* = 9.9 (Β±2.4) J K^βˆ’1^ mol^βˆ’1^and __k__ (200 K) = 2.94 (Β±0.09)Γ— 10^4