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Mechanism of the cis?trans isomerization in metathesis of olefins

✍ Scribed by Bilhou, J. L.; Basset, J. M.; Mutin, R.; Graydon, W. F.

Book ID
121194948
Publisher
The Royal Society of Chemistry
Year
1976
Tongue
English
Weight
209 KB
Volume
23
Category
Article
ISSN
0022-4936

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πŸ“œ SIMILAR VOLUMES

Mechanistic Insights into the cis–trans
Mechanistic Insights into the cis–trans Isomerization of Ruthenium Complexes Relevant to Catalysis of Olefin Metathesis
✍ Dr. Albert Poater; Dr. Francesco Ragone; Dr. Andrea Correa; Dr. Anna Szadkowska; πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 647 KB

## Abstract The mechanism of the __trans__ to __cis__ isomerization in Ru complexes with a chelating alkylidene group has been investigated by using a combined theoretical and experimental approach. Static DFT calculations suggest that a concerted single‐step mechanism is slightly favored over a mu