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Cis-trans isomerization of polybutadiene double bonds during olefin metathesis

✍ Scribed by Kumar, V. G. ;Hummel, K.


Publisher
John Wiley and Sons
Year
1983
Weight
507 KB
Volume
21
Category
Article
ISSN
0360-6376

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## Abstract The mechanism of the __trans__ to __cis__ isomerization in Ru complexes with a chelating alkylidene group has been investigated by using a combined theoretical and experimental approach. Static DFT calculations suggest that a concerted single‐step mechanism is slightly favored over a mu