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Cis-trans isomerization of polyisoprene-3-d, and the question of double bond migration during isomerization

✍ Scribed by Golub, M. A.

Publisher: Wiley (John Wiley & Sons)
Year: 1966
Tongue: English
Weight: 162 KB
Volume: 4
Category: Article
ISSN: 0449-2986
DOI: 10.1002/pol.1966.110040313

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The rate constants of isomerization, k and k', were determined at 68 "C to be 3.7 x s-', respectively. The activation energy is 30 kcal. mol -'. The re-