Mechanism of the backbone rearrangement of amino steroids. A carbon-13 and tritium nuclear magnetic resonance spectroscopic study of isoconessine, neoconessine and the corresponding polydeuterated and polytritiated species
β Scribed by Frappier, Francois; Audinot, Marcel; Beaucourt, Jean Pierre; Sergent, Leila; Lukacs, Gabor
- Book ID
- 126294451
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 361 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
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The '3C N M R spectra of sixteen 4-ene-3-keto-and 1,4-diene-3-keto corticosteroids are described. Substituent shifts and the effect of added methanol-d, are reported, and conformational distortions and intramolecular hydrogen bonding are analysed based on these data. DISCUSSION ## Substituent eff
## Abstract The carbonβ13 NMR spectra of some __N__β(2β or 4βnitrophenyl) tertiary amines and their corresponding __N__βoxides have been analysed. These __N__βoxides undergo thermal rearrangement to __O__βarylhydroxylamines, for which the ^13^C NMR spectral assignments were also carried out. The __