𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanism of reactions of unsaturated ethers and thioethers X: Neighbouring group effect in the acid-catalyzed rearrangement of ethoxyethynyl carbinols

✍ Scribed by G. L. Hekkert; W. Drenth

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
197 KB
Volume
82
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Mechanism of reactions of unsaturated et
Mechanism of reactions of unsaturated ethers and thioethers IV: Acid catalyzed rearrangement of ethoxyethynyl- and ethylthioethynyl-carbinols
✍ G. L. Hekkert; W. Drenth 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 810 KB

## Abstract The rearrangement of ethoxyethynyl‐carbinols into unsaturated esters was investigated in acidic aqueous solution. The reaction is general acid catalyzed and β‐hydroxy esters are by‐products. There exists a simple relation between the ratio of β‐hydroxy ester to unsaturated ester and the