Mechanism of production of electronically excited BaO in the reaction of Ba vapor with O2
โ Scribed by R.H. Obenauf; C.J. Hsu; H.B. Palmer
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 324 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Addition of Oz(iAg) to the reacting mixture of NHs and F atoms,is found to produce the NF(b 'X3 radicals, identified by the light emission at 529 and 562 nm. The energy transfer process Oz('Ag) + NF(a 'A& + 02 + NF(b IX+) explains the light emission.
A mixture of NF3 and Ar is passed through an rf discharge in a flowAystern to product, among other species, F and NFz. When Ha, D?;, or CH? are added downstream, reactions with F atoms poduce vibratiomlly esci:ed HI: or DF together with H, D, or CHJ. The latter free radicais can react with NF2, pro
The reaction of CH2, particularly the ground electronic state triplet CH2 [l], with 0 2 is known to be very fast. The effectiveness of the reactions involving both singlet (lCH2) and triplet (3CH2) methylene was most dramatically demonstrated by the drastic effects of O2 on CO laser emissions in bot