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Mechanism of photosubstitution in rhodium(III) chloroammines

✍ Scribed by Kutal, Charles; Adamson, Arthur W.

Book ID
126972086
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
488 KB
Volume
12
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Mechanism of photosubstitution reactions
Mechanism of photosubstitution reactions of square-planar platinum(II) complexes. III. Steric effects on the photosubstitution mechanism of bromo(1,1,7,7-tetraethyldiethylenetriamine)platinum(II) complex ion [1]
✍ C. Bartocci; A. Ferri; V. Carassiti; F. Scandola πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 457 KB

## The photosubstitution reactions of Pt(Et4dien)Br' have been investigated in aqueous solution by irradiation with 313 nm light. Pt(Et4dien)Hz02' was always formed in acid or neutral solutions, independently of the presence of CT (up to 1 X IO* M) or Br-(up to 1 X 1 0e2 M). Pt(Et,dien)OH' was forme