Mechanism of lactic acid formation catalyzed by tetraamine rhodium(III) complexes
✍ Scribed by Jette Eriksen; Ole Mønsted; Lene Mønsted
- Book ID
- 110244978
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 120 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g
In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.