The oxidative polymerization of aniline in aqueous acidic solution was carried out in the presence of a variety of organic compounds as potential traps for postulated intermediates. The polymerization was inhibited by hindered phenols and electron-rich alkenes, traps for cation-radicals. However, po
✦ LIBER ✦
Mechanism of organometallic radical trapping. The oxidative addition of quinones to photogenerated CpTiCl2•
✍ Scribed by A. Vlček Jr.
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 569 KB
- Volume
- 297
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The chemical reduction of Pt(acac)~2~ by DIBALH in the presence of phosphanes, which is used to generate active Pt^0^ complexes in the Pt‐catalyzed silaboration of cyclohexadiene by 2‐(dimethylphenylsilyl)‐4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane (1) leading to the 1,4‐silaborated produc