✦ LIBER ✦

Mechanism of nucleophilic substitution at silicon: kinetic evidence on the slow formation of a pentacoordinate silicon intermediate

✍ Scribed by Robert J.P. Corriu; Bernard J.L. Henner

Book ID: 108351510
Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 586 KB
Volume: 102
Category: Article
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)89384-5

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

On the evidence for intramolecular ligan

On the evidence for intramolecular ligand exchange in pentacoordinate carbonate (IV) anion: Implications for the mechanism of bimolecular nucleophilic substitution at saturated carbon.

✍ Cynthia A. Maryanoff; Fumio Ogura; Kurt Mislow 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 162 KB

Pentacoordinated molecules. 62. Acyclic

Pentacoordinated molecules. 62. Acyclic substituent effects on the molecular structure of cyclic-containing five-coordinated anionic silicates; a model for nucleophilic substitution at silicon

✍ Holmes, Robert R.; Day, Roberta O.; Chandrasekhar, V.; Harland, John J.; Holmes, 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 626 KB

Use of the 2,6-Bis[(dimethylamino)methyl

Use of the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand for the Study of Nucleophilic Substitution at Hexacoordinate Silicon Centers. Evidence Suggestive of a Heptacoordinate Silicon Transition State

✍ Carre, Francis; Chuit, Claude; Corriu, Robert J. P.; Fanta, Alan; Mehdi, Ahmad; 📂 Article 📅 1995 🏛 American Chemical Society 🌐 English ⚖ 593 KB

Nucleophilic substitutions at silicon :

Nucleophilic substitutions at silicon : Evidence for ion-pair dissociation as controlling factor of the stereochemistry and a simple mechanistic proposal

✍ R.J.P. Corriu; C. Guérin 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 635 KB

On the use of “fast kinetics” to determi

On the use of “fast kinetics” to determine the mechanism of ligand substitution at a solvated transition-metal intermediate

✍ Richard H. Schultz 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 113 KB

## Abstract Substitution of the weakly‐coordinated solvent molecule at a solvated transition‐metal intermediate is frequently investigated by “fast kinetic” methods. In typical experiments, the kinetics of the reaction are determined by following the time dependence of the changes in the reaction m

Evidence for a Radical Mechanism in Mono

Evidence for a Radical Mechanism in Monolayer Formation on Silicon Ground (or Scribed) in the Presence of Alkyl Halides

✍ Jiang, Guilin; Niederhauser, Travis L.; Fleming, Steven A.; Asplund, Matthew C.; 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 134 KB