Mechanism of Narrowly Dispersed Latex Formation in a Surfactant-Free Emulsion Polymerization of Styrene in Acetone–Water Mixture
✍ Scribed by Li, Zhiyong; Cheng, He; Han, Charles C.
- Book ID
- 120257252
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 525 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Emulsifier‐free emulsion polymerization of styrene in acetone–water medium was carried out using potassium persulfate as initiator. Below acetone content of 40 vol %, stable emulsion was prepared and polymerizations were remarkably fast compared with those in pure water. The particle si
Free radical dispersion polymerization of styrene in a mixture of 2-propanol and tetrahydrofuran was carried out at 70°C up to high conversions. The influence of the change of the critical chain length on the evolution of the insoluble polymer component was examined. Monomer conversion and the forma