Mechanism of N-vinylcarbazole polymerization on Co(II)–13X molecular sieve
✍ Scribed by Biswas, Mukul ;Banerjee, Madhusudan ;Maiti, Mrinal M.
- Publisher
- John Wiley and Sons
- Year
- 1985
- Weight
- 546 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0360-6376
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The polymerization of N-vinylcarbazole by 13X molecular sieves modified by five different transition metal ions, viz. Mn(II), Co(II), Ni(II), Cu(II) and Zn(II), has been studied under various conditions. The order of reactivity follows the trend: Mn(II)~ Cu(II) > Co(II)> Zn(II)> Ni(II) at pH ~ 3.55
## Abstract Copolymerizations of __N__‐vinylcarbazole with both isobutyl vinyl ether and __N__‐vinyl‐pyrrolidone initiated by some organic electron acceptors have been investigated for the purpose of elucidating the propagation mechanism in the charge‐transfer polymerization. Copolymerizations of t