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Mechanism of charge–transfer polymerization. II. Propagation mechanism of the polymerization of N-vinylcarbazole with organic electron acceptors

✍ Scribed by Fujimatsu, Masaaki ;Natsuume, Tadao ;Hirata, Hirotaka ;Shirota, Yasuhiko ;Kusabayashi, Shigekazu ;Mikawa, Hiroshi

Publisher: Wiley (John Wiley & Sons)
Year: 1970
Tongue: English
Weight: 476 KB
Volume: 8
Category: Article
ISSN: 0449-296X
DOI: 10.1002/pol.1970.150081127

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✦ Synopsis

Abstract

Copolymerizations of N‐vinylcarbazole with both isobutyl vinyl ether and N‐vinyl‐pyrrolidone initiated by some organic electron acceptors have been investigated for the purpose of elucidating the propagation mechanism in the charge‐transfer polymerization. Copolymerizations of the same system catalyzed by authentic cationic catalysts have also been made for comparison. The results indicate that the propagation mechanism of the charge‐transfer polymerization studied is catio ie.

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