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Mechanism of methanol synthesis from CO2/CO/H2 mixtures over copper/zinc oxide/alumina catalysts: use of14C-labelled reactants

✍ Scribed by G.C. Chinchen; P.J. Denny; D.G. Parker; M.S. Spencer; D.A. Whan


Book ID
119510207
Publisher
Elsevier Science
Year
1987
Weight
279 KB
Volume
30
Category
Article
ISSN
0166-9834

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A kinetic model for the deactivation of copper/zinc oxide catalyst during the methanol synthesis has been developed. This model is of the Langmuir-Hinshelwood-Hougen-Watson type and considers two types of active sites for the deactivation of catalyst. One of the site types on copper is allocated for