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Mechanism of isocyanide insertion into the methyl-iron bond of [Fe(CO)2L2(CNR)CH3]BPh4

✍ Scribed by Bellachioma, Gianfranco; Cardaci, Giuseppe; Macchioni, Alceo; Reichenbach, Gustavo


Book ID
120399769
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
494 KB
Volume
31
Category
Article
ISSN
0020-1669

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Activation of dithioformate by iron comp
✍ Dilip V. Khasnis; Nadine Pirio; Daniel Touchard; LoΓ―c Toupet; Pierre H. Dixneuf πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 896 KB

BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond