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Mechanism of hydrolysis of acetylcholine catalyzed by acetylcholinesterase and by hydroxide ion

✍ Scribed by Sylvia S. Stein; D.E. Koshland Jr.

Book ID: 119404299
Publisher: Elsevier Science
Year: 1953
Tongue: English
Weight: 106 KB
Volume: 45
Category: Article
ISSN: 0003-9861
DOI: 10.1016/s0003-9861(53)80024-x

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## Abstract Acylation of acetylcholine (ACh) catalyzed by acetylcholinesterase (AChE) has been studied using high‐level theoretical calculations on a model system that mimics the reaction center of the enzyme, and compared with uncatalyzed acylation reaction. The geometries of all the intermediates