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Mechanism of formation of Grignard reagents. The rate of reaction of cyclopentyl bromide with magnesium is transport limited in diethyl ether

โœ Scribed by Rogers, Harold R.; Deutch, John; Whitesides, George M.


Book ID
121415395
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
789 KB
Volume
102
Category
Article
ISSN
0002-7863

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m001d Ia UK for p9bli@8tlm 25 Ilo~~b~ 1975) The reaction of methylmagnesium bromide with aromatic ketones has been the subject of intense mechanistic studies in recent years.2 Since methylmagnesium bromide possesses no S-hydrogen atom, it is incapable of reducing ketones by S-hydrogen reduction and