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Mechanism of formation of 2-furaldehyde from d-xylose

✍ Scribed by Michael Jerry Antal Jr.; Tongchit Leesomboon; William S. Mok; Geoffrey N. Richards


Book ID
102997450
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
985 KB
Volume
217
Category
Article
ISSN
0008-6215

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Hydrothermal formation of 1,2,4-benzenet
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Thermolysis of 0.05 M aqueous 5-hydroxymethyl-2-furaldehyde (HMF) at 27.5 MPa and 290 to 400Β°C led to the formation of 1,2,4-benzenetriol in yields of up to 46% at 50% HMF conversion. The reaction temperature and water density have a significant effect on the product composition. Pseudofirst-order r