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Mechanism of electrochemical oxidation of 1-chloro-2,2,6,6-tetramethylpiperidine

✍ Scribed by E. Sh. Kagan; V. V. Yanilkin; V. I. Morozov; N. V. Nastapova; I. Yu. Zhukova; I. I. Kashparov; V. P. Kashparova


Book ID
111460108
Publisher
Springer
Year
2009
Tongue
English
Weight
154 KB
Volume
79
Category
Article
ISSN
1070-3632

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Mechanism of the oxidation of alcohols b
✍ M.F. Semmelhack; Christopher R. Schmid; David A. CortΓ©s πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 275 KB

Simple Hammett studies, hydrogen isotope effects, and attempted preparation of proposed transient intermediates are used to probe the mechanism of oxidation of alcohols by 2,2,6,6\_tetramethylpiperidine nitrosonium ion. The oxidation of alcohols to aldehydes and ketones with 2,2,6,6-\_ztramethylpip