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Mechanism of decarboxylation of 1,3-dimethylorotic acid. Possible role for orotate decarboxylase

โœ Scribed by Beak, Peter.; Siegel, Brock.

Book ID
127322329
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
271 KB
Volume
95
Category
Article
ISSN
0002-7863

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The deearboxylafion of 1,3-dimethylorotic acid was investigated to study the nature of the reaction intermediate. 6-Benzyl-l,3-dimethyluracil was isolated when the deearboxylation was carried out in benzyl bromide, indicating.the involvement of a carbon-6 centered nucleophilic intermediate in the re