Vernolic acid was prepared enantiospecifically from a readily available hydrate precursor and isomerized to (+)-coriolic acid using the methylmagnesium salt N-cyclohexylisopropylamine. Recently, (-)-vernolic acid' ( ) and (+)-coriolic acid2'3 (6) have attracted carboof
Mechanism of corn hydroperoxide isomerase: detection of 12,13(S)-oxido-9(Z),11-octadecadienoic acid
β Scribed by Mats Hamberg
- Book ID
- 115739874
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 870 KB
- Volume
- 920
- Category
- Article
- ISSN
- 0005-2760
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## Abstract The asymmetric __Sharpless__ epoxidation of methyl 13__S__βhydroxyβ9__Z__, 11__E__βoctadecaβdienoate (13__S__βHODE, **1**) with __tert__βbutyl hydroperoxide (TBHP) catalysed by titanium tetraisopropoxide {Ti(^__i__^OPr)~4~} in the presence of L(+)βdiisopropyl tartrate (LβDIPT) gave meth
An unstable fatty acid allene oxide, 12,13(S)-epoxy-Y(Z).1 I-octadecadienoic acid. was recently identified as the product formed from 13(S)-hydroperoxy-9(Z), I I(E)-octadecadienoic acid in the presence of corn (Zra rnu~s L.) hydroperoxide dehydrase (M. Hamberg ( 19X7) Biochim. Biophys. Acta 920, 768
Enantiocontrolled Synthesis of (11S,12S,13S)-(9Z,15Z)-and (11R,12S,13S)-(9Z,15Z)-11-Hydroxy-12,13-epoxy Octadecadienoic Acids by Means of the Sharpless Asymmetric Epoxidation of the Unsymmetrical Divinylcarbinol. -The enantioselective synthesis of the title compounds (V) and (VI), self-defensive su