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Mechanism of copolymerization of sulphur dioxide with olefins, initiated by hydroperoxides

✍ Scribed by E.C. Eaton; K.J. Ivin

Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
58 KB
Volume
5
Category
Article
ISSN
0032-3861

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Ethylene ketals of the type (I) cyclise in presence of phosphorus pentoxide in pyrid& to give the ketal (II) which on hydrolysis yields l-phenyl-6:7-dimethoxy4oxo-3:4-dihydroisquinob (III). 1-(4-oxo-cyclohexyl)-6:7-dimethoxy-3:4-dihydroisoquinoline (Vlll) and 2-oxo-3-methyl-g:1& dimethoxy-I 2:3:4:6: