Mechanism of chemiluminescence from peroxy radicals
β Scribed by Kellogg, Reid E.
- Book ID
- 127071152
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 448 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Existing data on the self-reactions of tertiary peroxy radicals ROn has been reanalyzed and corrected to deduce Arrhenius parameters for both termination and nontermination paths. For R = t-Rutyl, these are logk,(M-'sec-') = 7.1 -(7.0/8) and logknt(A4-'sec-') = 9.4 -(9.0/0), respectively, different
## Abstract An iterative method has been devised for the simulation of chemiluminescence data during the oxidative decomposition of Ξ±Ξ±β² azobisisobutyronitrile in the presence of ethylbenzene. From this simulation the cross termination rate constant of the two types of peroxy radicals present has be