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Electronic structure of some peroxy radicals

✍ Scribed by Stanislav Biskuič; Ladislav Valko

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
568 KB
Volume
27
Category
Article
ISSN
0022-2860

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📜 SIMILAR VOLUMES

The kinetics of the interaction of perox
The kinetics of the interaction of peroxy radicals. I. The Tertiary Peroxy Radicals
✍ Prakash S. Nangia; Sidney W. Benson 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 807 KB

Existing data on the self-reactions of tertiary peroxy radicals ROn has been reanalyzed and corrected to deduce Arrhenius parameters for both termination and nontermination paths. For R = t-Rutyl, these are logk,(M-'sec-') = 7.1 -(7.0/8) and logknt(A4-'sec-') = 9.4 -(9.0/0), respectively, different

The kinetics of the interaction of perox
The kinetics of the interaction of peroxy radicals. II. Primary and secondary alkyl peroxy
✍ Prakash S. Nangia; Sidney W. Benson 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 656 KB

## Abstract A chain mechanism is proposed to account for the very rapid termination reactions observed between alkyl peroxy radicals containing α‐C—H bonds which are from 10^4^ to 10^6^ faster than the termination of tertiary alkyl peroxy radicals. The new mechanism is equation image with termina