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Mechanism of 2,2′6,6′-Tetramethylpiperidin- N -oxyl-Mediated Oxidation of Alcohols in Ionic Liquids

✍ Scribed by Comminges, Clement; Barhdadi, Rachid; Doherty, Andrew P.; O’Toole, Sarah; Troupel, Michel


Book ID
127113591
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
165 KB
Volume
112
Category
Article
ISSN
1089-5639

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Mechanism of the oxidation of alcohols b
✍ M.F. Semmelhack; Christopher R. Schmid; David A. Cortés 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 275 KB

Simple Hammett studies, hydrogen isotope effects, and attempted preparation of proposed transient intermediates are used to probe the mechanism of oxidation of alcohols by 2,2,6,6\_tetramethylpiperidine nitrosonium ion. The oxidation of alcohols to aldehydes and ketones with 2,2,6,6-\_ztramethylpip