Mechanism for the Regioselective Asymmetric Addition of Grignard Reagents to Malimides: A Computational Exploration ‖
✍ Scribed by Ye, Jian-Liang; Huang, Pei-Qiang; Lu, Xin
- Book ID
- 126451545
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 303 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The copper-catalyzed conjugate addition of Grignard reagents to enones in the presence of chiral diselenide oxazoline ligands has been studied and found to provide good yields and useful levels of asymmetric induction.
## Abstract For Abstract see ChemInform Abstract in Full Text.
The copper catalyzed conjugate addition of n-butyl Grignard to enones in the presence of chiral ferrocenyl phosphine oxazoline ligands has been studied and found to provide useful levels of asymmetric induction. A comparison of the ferrocene derived ligands 3 and 6 with the corresponding phenyl deri