Chiral Diselenide Ligands for the Asymmetric Copper-Catalyzed Conjugate Addition of Grignard Reagents to Enones.
โ Scribed by Antonio L. Braga; Sandra J. N. Silva; Diogo S. Luedtke; Roberta L. Drekener; Claudio C. Silveira; Joao B. T. Rocha; Ludger A. Wessjohann
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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Copper-Catalyzed Asymmetric Conjugate Addition of Organometallic Reagents to Linear Enones Using Thiourethane Ligands. -The conjugate addition of organometals (cf. AlMe 3 ) to simple ฮฑ,ฮฒ-unsaturated enones such as (I) in the presence of chiral thiourethane ligands provides the corresponding ฮฒ-subst