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ChemInform Abstract: Copper-Catalyzed Asymmetric Conjugate Addition of Organometallic Reagents to Linear Enones Using Thiourethane Ligands.

✍ Scribed by Simon M. W. Bennett; Stephen M. Brown; James P. Muxworthy; Simon Woodward

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Copper-Catalyzed Asymmetric Conjugate Addition of Organometallic Reagents to Linear Enones Using Thiourethane Ligands.

-The conjugate addition of organometals (cf. AlMe 3 ) to simple Ξ±,Ξ²-unsaturated enones such as (I) in the presence of chiral thiourethane ligands provides the corresponding Ξ²-substituted compounds. However, only moderate enantioselectivities can be realized for these difficult substrates. -(BENNETT, SIMON

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v