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Mechanism for the reaction between cyanide and nickel(II) triglycine

✍ Scribed by Pagenkopf, Gordon K.

Book ID
126985815
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
471 KB
Volume
13
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Kinetics and Mechanism of the Demetallat
Kinetics and Mechanism of the Demetallation of Macrocyclic Nickel(II) Complexes by Cyanide
✍ Liselotte Siegfried; Thomasβ€…A. Kaden πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 114 KB πŸ‘ 1 views

## Abstract The kinetics and the mechanism of the cyanide‐induced demetallation of a series of Ni^2+^ complexes with macrocyclic ligands of different ring size (12‐ to 14‐membered; see **1**–**4**) and steric constraints was studied. Although the rates differ by almost five orders of magnitude when