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Mechanism for semiquinone formation in the oxygen negative chemical ionization mass spectrometry of 2,3,7,8-tetrachlorodibenzo-p-dioxin

✍ Scribed by Ronald K. Mitchum; Walter A. Korfmacher; James R. Althaus


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
367 KB
Volume
19
Category
Article
ISSN
1076-5174

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✍ Magda Claeys; Martine van Audenhove; Maurits Vandewalle 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 231 KB

## Abstract An oxygen to oxygen acyl migration has been observed in 7‐acetoxybicyclo|3,2,0|heptan‐2‐ones upon isobutane chemical ionization mass spectrometry. The mechanism of this rearrangement is discussed and is investigated by means of deuterium labelling techniques.