✦ LIBER ✦
Evidence for the occurrence of an oxygen to oxygen acyl shift in 7-acetoxybicyclo|3,2,0|heptan-2-ones upon chemical ionization mass spectrometry
✍ Scribed by Magda Claeys; Martine van Audenhove; Maurits Vandewalle
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 231 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0037-9646
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✦ Synopsis
Abstract
An oxygen to oxygen acyl migration has been observed in 7‐acetoxybicyclo|3,2,0|heptan‐2‐ones upon isobutane chemical ionization mass spectrometry. The mechanism of this rearrangement is discussed and is investigated by means of deuterium labelling techniques.