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Mechanism and kinetics of the acid-catalyzed formation of ethene and diethyl ether from ethanol in supercritical water

✍ Scribed by Xu, Xiaodong; De Almeida, Carlos P.; Antal, Michael Jerry

Book ID
125856696
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
980 KB
Volume
30
Category
Article
ISSN
0888-5885

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πŸ“œ SIMILAR VOLUMES

Mechanism and kinetics of the acid-catal
Mechanism and kinetics of the acid-catalyzed dehydration of ethanol in supercritical water
✍ Xiaodong Xu; Carlos De Almeida; Michael J. Antal Jr. πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 472 KB

In the presence of a low concentration (<O.Ol mol dm-3) of sulfuric acid, ethanol undergoes rapid and selective dehydration to ethene in supercritical water. The kinetics of this reaction are consistent with an acid-catalyzed E2 mechanism.