Mechanism and Kinetics of RAFT-Based Living Radical Polymerizations of Styrene and Methyl Methacrylate
โ Scribed by Goto, Atsushi; Sato, Koichi; Tsujii, Yoshinobu; Fukuda, Takeshi; Moad, Graeme; Rizzardo, Ezio; Thang, San H.
- Book ID
- 115454705
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 97 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** Radical homopolymerizations and copolymerizations of styrene were performed in toluene and __N__,__N__โdimethylformamide (DMF) as solvents using different initiators with and without microwave irradiation. Only the homopolymerization of styrene under microwave irradiation i
## Abstract Organostibineโmediated controlled/living radical polymerization of MMA was successfully achieved in room temperature ionic liquids (RTILs) [bmim]Tf~2~N and [bmim]PF~6~. The ln([M]~0~/[M]) increased linearly with increasing reaction time. The numberโaverage molecular weights of PMMA incr