𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanism and Energetics of Intramolecular Hydrogen Transfer in Amide and Peptide Radicals and Cation-Radicals

✍ Scribed by Tureček, František; Syrstad, Erik A.

Book ID
120794969
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
544 KB
Volume
125
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Rearrangements in Model Peptide-Type Rad
Rearrangements in Model Peptide-Type Radicals via Intramolecular Hydrogen-Atom Transfer
✍ Damian Moran; Rebecca Jacob; Geoffrey P. F. Wood; Michelle L. Coote; Michael J. 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 743 KB

## Abstract Intramolecular H‐atom transfer in model peptide‐type radicals was investigated with high‐level quantum‐chemistry calculations. Examination of 1,2‐, 1,3‐, 1,5‐, and 1,6[C ↔ N]‐H shifts, 1,4‐ and 1,7[C ↔ C]‐H shifts, and 1,4[N ↔ N]‐H shifts (__Scheme 1__), was carried out with a number of