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Intramolecular addition and hydrogen atom transfer reactions of aryl radicals

✍ Scribed by Beckwith, Athelstan L. J.; Gara, W. B.


Book ID
126300202
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
212 KB
Volume
91
Category
Article
ISSN
0002-7863

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## Abstract Intramolecular H‐atom transfer in model peptide‐type radicals was investigated with high‐level quantum‐chemistry calculations. Examination of 1,2‐, 1,3‐, 1,5‐, and 1,6[C ↔ N]‐H shifts, 1,4‐ and 1,7[C ↔ C]‐H shifts, and 1,4[N ↔ N]‐H shifts (__Schemeβ€…1__), was carried out with a number of