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Mechanical properties and morphology of the modified HDPE/starch reactive blend

✍ Scribed by Byung Chul Jang; Soo Young Huh; Jeong Gyu Jang; Young Chan Bae


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
298 KB
Volume
82
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

We investigated the effect of reactive blending on the mechanical properties and morphology of high‐density polyethylene (HDPE)/plasticized starch blends. HDPE was chemically modified to enhance the compatibility with the plasticized starch. The modified HDPE, HDPE‐g‐glycidyl methacrylate (GMA), was synthesized by melt reaction of HDPE in the presence of dicumyl peroxide (DCP). A finer dispersion of starch in the HDPE matrix was achieved compared to that in the unmodified HDPE. The amount of GMA groups in the modified HDPE enhanced the miscibility of HDPE/starch blends. We also observed that the amount of glycerin improves the mechanical properties of blends. Β© 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 3313–3320, 2001


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