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Mechanical activation of the KOH-DMSO superbase system and its use in the reaction with cyclohexanone

✍ Scribed by B. A. Trofimov; A. M. Vasil'tsov; A. I. Mikhaleva; O. V. Petrova; A. V. Polubentsev


Book ID
112449573
Publisher
Springer
Year
1989
Tongue
English
Weight
95 KB
Volume
38
Category
Article
ISSN
1573-9171

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The reaction of red phosphorus with 1-br
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## Abstract Red phosphorus reacts with 1‐bromonaphthalene in the KOH–DMSO system upon heating (47–70Β°C, 3 h) to give tri(1‐naphthyl)phosphane in 10% yield. Microwave activation (600 W, 6 min) of the reaction affords the above‐mentioned phosphane in 25% yield. Β© 2011 Wiley Periodicals, Inc. Heteroat