The absolute rate constants have been measured for several gas-phase chlorine atommolecule reactions a t 25OC by resonance fluorescence. These reactions and their corre- sponding rate constants in units of cm3 mole-' sec-l are: The effects of varying the substrate pressure, total pressure, light in
Measurements in N2CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study
✍ Scribed by A. Ricard; G. Cernogora; M. Fitaire; L. Hochard; N. Kouassi; C. Speller; J.R. Vacher
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 585 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0032-0633
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The rate consorts of several H=O+ reactions have been measured as a function of relative kinetic energy in a ffow&ift tube The reactions were found to proceed in a variety of ways -charge transfer, proton transfer. and H-aom &strxtton and to have onl) moderate kinetic-energy dependences.
Pulsed laser photolysis, time-resolved laser-induced fluorescence experiments have been carried out on the reactions of CN radicals with CH,, CZHs, C2H4, C3H6, and C2H2. They have yielded rate constants for these five reactions at temperatures between 295 and 700 K. The data for the reactions with m