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Mn2+ EPR study of phase transitions occurring in single crystals of [N(CH3)4]2ZnCl4, [N(CH3)4]2ZnBr4, [N(CH3)4]2CoBr4, [N(C2H5)4]2ZnCl4, [N(C2 H5)4]2ZnBr4, [N(C2H5)4]2CoBr4 and [N(C2H5)4]2MnBr4

✍ Scribed by Mojtaba Kahrizi; Sushil K. Misra; Jerzy Kotlinski; M.O. Steinitz; Truis Smith-Palmer

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
516 KB
Volume
79
Category
Article
ISSN
0038-1098

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Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t