Measurement of the organic nitrate yield from OH reaction with isoprene
β Scribed by Chen, Xiaohui; Hulbert, David; Shepson, Paul B.
- Book ID
- 119697039
- Publisher
- American Geophysical Union
- Year
- 1998
- Tongue
- English
- Weight
- 680 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0148-0227
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The rate of the gas phase reaction of hydroxyl radical with methyl nitrate has been measured to be (3.4 \* 0.4) x cm3 molecule-' s-' at 298 K using flow discharge/ resonance fluorescence techniques. By means of correlation methods, this rate determination is used to predict a vertical ionization pot
## Οͺ12 Οͺ1 Οͺ1 9 Ο« 10 mol s of 2) for the reaction of isoprene-based hydroxyalkyl peroxy radicals with NO.
The products of the reaction of OH with CHsSSCH3 (DMDS) were investigated at 298 K using a flow tube reactor coupled to a photoionization mass spectrometer and a pulsed photolysis-pulsed laser induced fluorescence apparatus. The results from the former apparatus were semi-quantitative and showed tha