Wilkinson et al. (1,2,3) found chlorotris(triphenylphosphine)rhodium(I) to be an active catalyst in the hydrogenation of olefinic and acetylenic bonds. A mechanism was advanced
Measurement of the activity of hydrogen and oxygen catalysts by a photochemical relaxation method
β Scribed by Neumann-Spallart, Michael
- Book ID
- 118026608
- Publisher
- The Royal Society of Chemistry
- Year
- 1985
- Weight
- 620 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0300-9589
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π SIMILAR VOLUMES
The reaction-velocity of hydrogen and oxygen at the surface of platinum in dependence on both gases was determined by measuring the change of pressure of the combustible gas. From the formula for the reaction-veldcity\*could be inferred the way in which both gases were adsorbed at the solid surface.
## Abstract The kinetics of hydrogenation of the acrylonitrileβpolybutadiene (NBR) rubber by the action of hydrazine in the presence of selenium and oxygen was studied by varying reaction parameters such as latex and catalyst concentrations. The method of initial rates gives a reaction order of 0.9