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Activation of the chlorotris(triphenylphosphine)rhodium(I) hydrogenation catalyst by oxygen or hydrogen peroxide

✍ Scribed by H. van Bekkum; F. van Rantwijk; T. van de Putte

Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 106 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97635-x

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✦ Synopsis

Wilkinson et al. (1,2,3) found chlorotris(triphenylphosphine)rhodium(I)

to be an active catalyst in the hydrogenation of olefinic and acetylenic bonds. A mechanism was advanced

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