Two methods are presented for obtaining rate constant of two-step reactions A, Ft A, Ft As by means of chemical relaxation technique when two relaxation times ate of the same order of magnitude. Both methods employ nonlinear estimation. The first method involves obtaining the relaxation times direct
โฆ LIBER โฆ
Measurement of rate constants of vibrational-rotational relaxation by the probing field method
โ Scribed by Yu. I. Bulgakov; A. I. Burshtein; A. V. Storozhev
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 363 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0021-9037
No coin nor oath required. For personal study only.
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The detailed spectroscopic study of transient free CF radicals with the resonance enhanced multiphoton ionization (REMPI) method is the aim of this paper. The CF radicals were generated from the gaseous (50-200 Pa) halocarbons CCl 3 F, CCl 2 F 2 , CClF 3 , 1,2-C 2 Cl 2 F 4 , C 2 ClF 3 , and C 6 F 6