The double nuclear quadrupole splitting structure in 2-chloroacrylonitrile was resolved in spectra recorded with a supersonic beam, cavity Fourier transform microwave spectrometer. Splitting patterns in both a-and b-type transitions were analyzed, and perturbations arising from the proximity of the
Measurement of Cl and N quadrupole coupling in ClCN
β Scribed by C.D Cogley; H.A Fry; S.G Kukolich
- Book ID
- 107801912
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 409 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
K = 1 + 0 transitions in CHsOD for / = 1, 2, 3 and 4 E,-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and / = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond di?ection of eqzzQ = 303 i 12 kHz.
The "N electric quadrupole coupling constants and asymmetry parameters have been detetmioed for the three chemicalIy oooequivalent nitrogen sites in both 4-(N,Ndimethyhunioo)-3-acetamidonitrobeozeoe (DAN) and ( -)-2-(a-methylbenzylomamino)-5-oitropyridine (MBANP) with the help of proton-nitrogen ouc