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[{MeAl(μ2-F)}2N(2,6-iPr2C6H3)]4— A Molecular Al-F-N Cage Compound

✍ Scribed by Helge Wessel; Hyung-Suh Park; Peter Müller; Herbert W. Roesky; Isabel Usón

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
103 KB
Volume
38
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

[{MeAl(μ2-F)}2N(2,6-iPr2C6H3)]4 – eine m
[{MeAl(μ2-F)}2N(2,6-iPr2C6H3)]4 – eine molekulare Al-F-N-Käfigverbindung
✍ Helge Wessel; Hyung-Suh Park; Peter Müller; Herbert W. Roesky; Isabel Usón 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB

AlN und AlF 3 sind hochschmelzende, temperaturbeständige Feststoffe und in organischen Lösungsmitteln unlöslich. In den letzten Jahren ist es jedoch gelungen, von beiden Verbindungen lösliche Vorstufen zu erhalten, die durch Eliminierung der organischen Reste unter relativ milden Bedingungen zu AlN

Synthesis and Structure of the Tetrameri
Synthesis and Structure of the Tetrameric [Cp*V(μ-F)2]4 (Cp* = C5Me5); Preparation of the Imido Molybdenum Fluoride [(2,6-i-Pr2C6H3N)2MoF2] · THF and the Structural Investigation of [(2,6-i-Pr2C6H3N)6Mo4(μ3-F)2Me2(μ-O)4]
✍ Haijun Hao; Herbert W. Roesky; Chunming Cui; Hans-Georg Schmidt; Mathias Nolteme 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 160 KB 👁 1 views

Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged