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[HC{(CMe)(NAr)}2]Al[(NSiMe3)2N2] (Ar=2,6-iPr2C6H3): The First Five-Membered AlN4 Ring System

✍ Scribed by Chunming Cui; Herbert W. Roesky; Hans-Georg Schmidt; Mathias Noltemeyer

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 96 KB
Volume: 112
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3757(20001215)112:24<4705::aid-ange4705>3.0.co;2-0

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[HC{(CMe)(NAr)}2]Al[(NSiMe3)2N2] (Ar=2,6

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[{HC(CMeNAr)2}2Al2P4] (Ar=2,6-iPr2C6H3):

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Polymerization of propylene was conducted at 0 -150°C with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel