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MCM-41-supported poly(γ-mercaptopropylsiloxane palladium(0)) complex as an efficient catalyst for Heck arylation of conjugated alkenes with aryl halides

✍ Scribed by Qiuhua Xu; Mingzhong Cai


Book ID
108257430
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
148 KB
Volume
67
Category
Article
ISSN
1381-5148

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A silica-supported poly-g-methylselenopropylsiloxane palladium complex has been prepared from g-chloropropyltriethoxysilane via immobilization on fumed silica, followed by reacting with sodium methylselenolate and then the reaction with palladium chloride. It is an efficient catalyst for Heck carbon