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MCM-41-supported bidentate phosphine palladium(II) complex as an efficient catalyst for the carbonylation of aryl halides

✍ Scribed by Wenyan Hao; Junchao Sha; Shouri Sheng; Mingzhong Cai


Book ID
119216562
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
240 KB
Volume
10
Category
Article
ISSN
1566-7367

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MCM-41-supported bidentate phosphine palladium(0) complex was conveniently synthesized from commercially available and cheap β₯aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydr

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A silica-supported poly-g-methylselenopropylsiloxane palladium complex has been prepared from g-chloropropyltriethoxysilane via immobilization on fumed silica, followed by reacting with sodium methylselenolate and then the reaction with palladium chloride. It is an efficient catalyst for Heck carbon