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MCD and absorption spectra of the monovalent anion of tribenzo [12] annulene

✍ Scribed by R.E. Koning; P.J. Zandstra

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
313 KB
Volume
56
Category
Article
ISSN
0009-2614

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✦ Synopsis

The magnetic circular dichrcism (MCD) and absorption spectra of the monovalent anion of tribenzo [ 121 annulene have been measured in the visiib and the near-infrared region. Ihe absence of a temperature dependence of the MCD proves a non-degenerate ground state. An as.sigrunent of the spectra has been given with the aid of a scmi-empiricat ~-eIectron caku-&ion (PPP approximation)_ Influence of the counter ion on optical and ESR spectra was tested by the use of different soivents. No divalent anions couId be obtained.

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